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their useful chiral allylic tin or indium reagents to the syntheses of three bis-THFcontaining acetogenin with a threo-trans-threo-trans-threo relative con guration (asimicin,47,48 asiminocin, asiminecin,49 and asimin50), one bis-THF-containing acetogenin with a erythro-trans-threo-trans-threo relative con guration [(30S)-bullanin51], and one bis-THF-containing acetogenin with a threo-cis-erythro-transthreo relative con guration (trilobin52) in the bis-THF region. Very recently, they developed a more exible and general strategy to synthesize these acetogenins with a bis-THF subunit (Scheme 10-18). Five acetogenins, asiminocin, asimin, asmicin, (5S)-uvarigrandin, and (5R)-uvarigrandin, could be cut into four fragments (A/B/C/D). Among these fragments, a masked di-aldehyde B is the common building block for these targets. Scheme 10-19 shows the synthesis of asimicin.58 The reaction of aldehyde 91 with allylic tin 92 in the presence of InBr3 afforded the anti- (or erythro)-adduct 93. Later, a similar reaction between aldehyde 94 and functionalized allylic tin 95 provided 96. Both newly born hydroxyl groups in the above reactions were masked as tosylate immediately. The threo-trans-threo-trans-threo bis-THF rings (in compound 97) were formed by treatment of the tosylate with TBAF. Coupling of the THF-containing segment 97 and lactone segment 98 was achieved with Sonogashira s conditions. If fragment A in Scheme 17 is treated rst with BF3 OEt2 and then subjected to aldehyde, the threo (syn) product will be produced predominantly. Thus, this methodology could be expanded for construction of those acetogenins with erythro (C-24/C-25) con guration. Scheme 10-20 illustrates the synthesis of bullanin53 and (30S)-hydroxybullatacin.54 In both cases, the reactions of allylic tins and aldehydes in the presence of InBr3 or BF3 OEt2 gave anti- or syn-adducts, respectively. Again, the Sonogashira reaction was applied into the skeleton establishment. Marshall et al. measured the activities of those bis-THF acetogenins synthesized against human cancer cells H-116 (Table 10-2). These results showed that the

Castro, P, P Chiu, T Kremenek, R Muntz (2001) A Probabilistic Room Location Service for Wireless Networked Environments Proceedings of the 3rd International Conference on Ubiquitous Computing, Atlanta, Georgia Springer-Verlag, 18 34 Chan, Y T, K C Ho (1994) A Simple and Ef cient Estimator for Hyperbolic Location IEEE Transactions on Signal Processing, Vol 42, No 8, 1905 1915 Chaum, D (1981) Untraceable Electronic Mail, Return Addresses and Digital Pseudonyms Communications of the ACM, Vol 24, No 2, 84 88..

1 T (12.56) (t , j ; st ) P (t , T ; st )r (t ; st ) cosh j =t + T ( t , j ; s t ) j = t+ if st +1 = st u e P (t + , T ; st + ) = (12.56) 1 T P (t , T ; s )r (t ; s ) cosh (t , j ; st ) t t j =t + T ( t , j ; s t ) e j = t+ if st +1 = st d

TAI-SHAN HU, YU-LIN WU,

energy quality. Special attention has to be given to the reduction of power and energy losses. The model of a subtransmission system presented in this section re ects loss reduction on DG sources located in distribution systems. Other legal and technical restrictions related to the integration and interconnection of DG are dealt with in s 12 and 15, respectively.

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50/53 44/47

>>> tup1=(123, abc ,345) >>> id(tup1) 17351292 >>> list1=list(tup1) >>> id(list1) 17454260

Column C contains the multipliers for each digit: alternating 2s and 1s. Column D contains formulas that multiply the digit in column B by the multiplier in column C. For example, the formula in cell D5 is: